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A diode array process analyzer, ammonia analyzer & NOx analyzer, ammonia slip analyzer

Ammonia Analyzer

Ammonia slip & NOX concentration   

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A diode array process spectrophotometer for the DeNOx process control

The flue gas stream contains ammonia, nitrogen oxides and in some cases sulfur dioxide 1. These components all absorb UV radiation, and therefore can be monitored by process analyzers that utilize UV absorbance techniques for detection such the ASA-400 ( incorporating a process diode array UV VIS spectrophotometer).

The full spectrum analysis advantage

The following figures  show the absorbance spectra of: ammonia, nitrogen oxide, nitrogen dioxide and a mixture of all three in a process stream, one can immediately see that the absorbance features strongly overlap. A full high resolution spectral analysis is, therefore, essential. High accuracy at a relatively wide dynamic range is achieved  due to the sharp absorbance features of the components measured by the high resolution process spectrophotometer.

Accuracy:

NH3 ±1ppm ; NO ±1ppm ;NO2 ± 1ppm

 
 
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ASA-400 Specifications

Use / Application Measurement of minute quantities of ammonia gas NH3 (slip stream), nitric oxide (NO), nitrogen dioxide (NO2) and sulfur dioxide (SO2).
Process DeNOx Catalytic and non catalytic removal of nitrogen oxides(SCR, SNCR).
Industry Power generating plants
Measurement mode Continuous on-line
Measurement range NH3 0-20ppm (± 1ppm) , SO2 0-2000ppm (± 3% of measurement) NO , NO2 0-600ppm (± 1% of measurement)
Measurement principle Diode array UV industrial spectrophotometer
Probe: Hastalloy - cross stack averaging (up to 8 meters long
Sample line 5 meters long (280 ° C) Hastalloy (other lengths - optional)
Output: RS-232 four 4-20mA galvanically isolated outputs.
Ambient temperature: -20 to 55 ° C

 

For more information:

View a Power Point presentation presented at the Boston SPIE 2001 : 

Continuous monitoring of Ammonia slip in DeNox processes; extending the detection limits of UV spectroscopy.

Please see ammonia in a DeNOx process

View PDF          View presentation

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